To correct the troubles I had, I did this clean setup :
1 - Erase users/shared/pixologix folder (be sure to save what’s in if needed)
2 - Erase applications/Zbrush 3.2 folder (be sure to save what’s in if needed)
3 - Reinstall.
4 - Some errors can occur at launch : be sure to have all authorizations (read&write) rights over the newly installed applications/Zbrush 3.2 folder. If not, change them.
5 - Be sure you have the same authorization over the /shared/pixologix folder
I hope it will help, everything works like a charm for me now !