I have no doubt that zBrush is a very cool programme and I can see that people get amazing results, but I am just about ready to give up and ask for my money back.
I have looked at videos and read and reread the user guide until I am cross-eyed. I cannot find any simple, step by step explanation of how to use materials and lights together to get the effect I am looking for, nor of how to reset lights to the default setting. I have to quite out of the programme to get rid of the lights I have set up. The user guide is not clear on how these things work, and their section on lights as opposed to lightcaps, is very poor. Does anyone know of somewhere where there is a really good explanation of
(a) how to get material modifiers to work with a subtool? I have a figure with fibermesh hair, and when I try and modify the materials of the figure, all it does is modify the hair, even thought the figure is selected in the subtool palette.
(b) how lights and materials work together and what results you get by changing onto the other? How can I get rid of the effect of plastic coating on my model as soon as I add lights? I’ve tried using basic materials, but the effect is always the same.
© how to get lights to work with all the subtools together and not just the selected subtool? 

There is so much to learn! Thank you again for taking the time to help.