I am following what the manual is saying
1. Select the PolyGroup Action
2. Select the A Single Poly Target
3. Hover over a polygon belonging to the desired PolyGroup.
4. While clicking and holding on this polygon, press (or tap) the Shift key. ZBrush
will copy the clicked polygon’s PolyGroup. Release the click.
5. Now click on another polygon to paste the PolyGroup.
But I can’t seem to copy a polygroup over. I tried different modifiers as well, no joy.